Aqua(4,5-dihydroxybenzene-1,3-disulfonato-κO)bis(1,10-phenanthroline-κ2 N,N’)cadmium(II) monohydrate
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چکیده
In the title compound, [Cd(C(6)H(4)O(8)S(2))(C(12)H(8)N(2))(2)(H(2)O)]·H(2)O, each Cd(II) ion is coordinated by four N atoms [Cd-N = 2.310 (7)-2.341 (7) Å] from two 1,10-phenanthroline ligands, one O atom [Cd-O = 2.300 (6) Å] from a 4,5-dihydroxy-benzene-1,3-disulfonate ligand and one aqua O atom [Cd-O = 2.288 (7) Å] in a distorted octa-hedral geometry. The crystal packing exhibits inter-molecular O-H⋯O and C-H⋯O hydrogen bonds and π-π inter-actions evidenced by relatively short distances [3.525 (5)-3.937 (6) Å] between the centroids of the six-membered rings of neighbouring mol-ecules.
منابع مشابه
Aqua(1,10-phenanthroline-κ2 N,N′)bis(trimethylacetato)-κ2 O,O′;κO-cobalt(II)
In the title compound, [Co(C(5)H(9)O(2))(2)(C(12)H(8)N(2))(H(2)O)], the Co(II) atom is coordinated in a distorted octahedral environment by three carboxyl O atoms of two trimethyl-acetate ligands, one aqua O atom and two N atoms from 1,10-phen-anthroline. The crystal structure is stabilized by O-H⋯O hydrogen bonds and π-π stacking inter-actions [inter-planar distance between inter-digitating 1,...
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The title compound, {[Mn(HCOO)(2)(C(12)H(8)N(2))(H(2)O)]·H(2)O}(n), consists of polymeric chains of the complex [Mn(HCOO)(2)(phen)(H(2)O)](∞) (phen is 1,10-phenanthroline) with solvent water mol-ecules. The chains contain six-coordinate Mn(II) ions bridged by formate anions. They are further extended into a three-dimensional network via O-H⋯O hydrogen-bonding inter-actions and inter-chain π-π s...
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The title compound, [Pb(2)(C(7)H(5)O(2))(2)(NO(3))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)], crystallizes as a dinuclear centrosymmetric dimer containing two Pb(II) atoms bridged by two benzoate ligands. Each Pb(II) atom is seven-coordinated by a water mol-ecule, a nitrate anion, a 1,10-phenanthroline (phen) ligand and two benzoate anions. The crystal packing is stabilized by O-H⋯O hydrogen bonds and by...
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In the mononuclear title complex, [Ni(C(14)H(6)O(8)S(2))(C(12)H(8)N(2))(2)(H(2)O)], the Ni(II) atom is in a distorted octa-hedral coordination formed by four N atoms from two chelating 1,10-phenanthroline ligands and by two O atoms, one from a 9,10-dioxoanthracene-1,5-disulfonate ligand and the other from a water mol-ecule. An intra-molecular O-H⋯O hydrogen bond occurs. In the crystal, inter-mo...
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In the asymmetric unit of the title complex, [Mn(C(7)H(5)O(3))(2)(C(14)H(12)N(2))(H(2)O)]·0.5C(14)H(12)N(2), the Mn(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) mol-ecule, one water mol-ecule and two monodentate 2-hydroxy-benzoate anions in a distorted trigonal-bipyramidal geometry. The OH group of the 2-hydroxy-benzoate anion is disordered over two positions ...
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